Mechanical shock-induced nucleation in solution: Is cavitation necessary?

نویسندگان

چکیده

Mechanical shock-induced nucleation (MSIN) of crystals from aqueous supersaturated solutions ammonium chloride is reported. A simple apparatus was constructed to expose in glass vials a single impact, while images were recorded using fast camera. strong correlation between cavitation the liquid and solid revealed. The measured fraction nucleated as function impact height fitted Poisson model. mean number solution samples increased quadratically with above threshold height. Analysis showed that accelerations achieved sufficient induce based on proposed by Pan et al. [Proc. Natl. Acad. Sci. USA 114 (2017) 8470]. use hydrophobic coating internal surface shown significantly increase both cavities observed probability MSIN crystals. results presented suggest salt mediated cavitation.

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ژورنال

عنوان ژورنال: Journal of Crystal Growth

سال: 2022

ISSN: ['1873-5002', '0022-0248']

DOI: https://doi.org/10.1016/j.jcrysgro.2022.126786